milan米兰体育官网入口
- Aiming to realize high-power thermoelectric generation module for effective utilization of waste heat -
NEDO, Thermal Management Materials and Technology Research Association (TherMAT), and milan米兰体育官网入口 Co. Ltd. have, in a world-first, developed a clathrate sintered body U-shaped element to realize thermoelectric generation in mid-high temperature range, and succeeded in generating electricity with a small flame like that of a candle.
Based on this development, milan米兰体育官网入口 of industrial furnaces and automobile engines in the medium-high 200 to 800°C temperature range, into electric power, and for application in other areas such as the household sector.
milan米兰体育官网入口 "2017 NEDO Energy Conservation Technology Forum" as part of "INCHEM TOKYO 2017" to be held from November 20 to 22 at Tokyo Big Sight, which will introduce the results of the latest energy conservation technology developments and efforts.
1. Overview
Currently, milan米兰体育官网入口 transportation, industry and household sectors, over half the primary energy goes unused and becomes waste heat. Against this backdrop, NEDO is focused on the enormous amount of unutilized heat that is emitted into the environment without being used, and since 2015 has been implementing a "Research and Development Project for Innovative Thermal Management Materials and Technologies"(note 1)that aims for the innovation of underlying technologies to make it possible to "Reduce, Recycle and Reuse" and to establish a system.
Now, in the NEDO project, milan米兰体育官网入口 Co., Ltd. (hereinafter, milan米兰体育官网入口), a member of the Thermal Management Materials and Technology Research Association (hereafter, TherMAT), in a world first, have developed a high temperature electrodeless U-shaped element with integrated P-type and N-type sintered bodies(note 2)composed of environmentally-friendly silicon clathrate compounds(note 3)(Fig. 3). Based on this development, durability is improved for use on the high-temperature side of the element (right side of Figure 1), and milan米兰体育官网入口 from industrial furnaces and automobile engines in the medium-high 200 to 800°C temperature range into electric power, and for application in other fields such as the household sector.
milan米兰体育官网入口 "2017 NEDO Energy Conservation Technology Forum" as part of "INCHEM TOKYO 2017" to be held from November 20 to 22 at Tokyo Big Sight, which will introduce the results of the latest energy conservation technology developments and efforts. For details, please refer to the below URL.
Holding of the “2017 NEDO Energy Conservation Technology Forum”:
http://www.nedo.go.jp/english/news/AA5en_100300.html
2. Results of the development
Thermoelectric conversion technology is technology that can obtain electric power directly from waste heat via the solid-state Seebeck effect(note 4), and it is expected that it will contribute to energy conservation by effectively utilizing unused 200 to 800°C heat milan米兰体育官网入口 so-called medium-high temperature range such as waste heat from factories and automobile engines. However, materials with high thermoelectric performance milan米兰体育官网入口 medium-high temperature range are mostly composed of elements that are highly toxic, rare and low melting, such as lead, tellurium, antimony, selenium, and thallium. Thermoelectric exchanger materials composed of these elements have not been widely used because they require ingenuity for use in air.
The high-temperature electrode-less U-shaped element (Figure 1) integrated with P-type and N-type sintered bodies made of environmentally-friendly silicon clathrate compounds developed here is composed mainly of silicon, the most abundant element on earth, and since both the P-type and N-type are made of the same type of silicon clathrate compound, there is no great difference in value milan米兰体育官网入口ir physical properties such as the coefficient of thermal expansion. Moreover, by eliminating the metal electrode on the high-temperature side and the insulating substrate from the conventional module, high temperature resistance has been attained. Holding this element over a flame such as a candle produces a voltage of 50 mV. Using 8 elements, we developed an 8-pair half-skeleton module in which the metal electrodes are arranged on the low-temperature side (right side in Figure 1) electrically in series and thermally in parallel, and in carrying out an experiment where the module was held over a candle flame (outer flame approx. 800°C), we succeeded in rotating a small motor (Figure 2 - refer to movie from QR code). From this it was found that electricity can be generated even milan米兰体育官网入口 absence of special auxiliary components for heat collection, dissipation, or atmospheric exposure.
In addition, the U-shaped element developed this time is specialized for a high-temperature region milan米兰体育官网入口 realm of exposure to direct flame, and it is expected to obtain power generation in micro-watt (μW) to kilo-watt (kW) levels by increasing the number of elements connected (Figure 3).
3. Future plans
The technology developed here can be applied not only to automobile exhaust heat and industrial waste heat but also to other fields. We will consider further development for further energy saving. As an example, Figure 4 shows a proposed compact power generation system installed in a stove. In combination with a portable stove that is a recommended disaster preparedness stockpile item, it is also expected that the technology can be used as a means to charge small electronic devices such as smartphones. Further, based on this development, we aim to realize a high-power thermoelectric generation module that converts unutilized thermal energy such as exhaust heat from industrial furnaces and automobile engines milan米兰体育官网入口 medium-high 200 to 800°C temperature range into electric power.
In material development, milan米兰体育官网入口 establish technologies to suppress the rise in electrical resistivity due to nanostructures.
We will experimentally confirm the improvement of the properties of the new material by sintered body trial manufacture and measurement. milan米兰体育官网入口ddition to better understanding the thermal cycle characteristics, we will also develop technologies to mount the sintered bodies at high density.
Glossary
(note 1)milan米兰体育官网入口
Under Project Leader Dr. Haruhiko Obara (National Institute of Advanced Industrial Science and Technology (AIST), Energy and Environment Research Strategy Department, Research Strategy Director), research and development of innovative technology is carried out from 2013-2022 (of which, 2013-2014 was carried out by the Ministry of Economy, Trade milan米兰体育官网入口dustry)
(note 2)milan米兰体育官网入口
A material that generates a positive (or negative) voltage when given a positive (or negative) milan米兰体育官网入口 P-type (or N-type), each of which is made from a sintered body.
(note 3)Clathrate compounds
Intermetallic compounds having a cage-like crystal structure with the basic chemical formula Ba8Ga16Ge30. Cage-like polyhedral encapsulating elements are, by forming cubic crystals while sharing their planes, considered to have the most ideal crystal structure as thermoelectric exchanger materials. They are attracting attention as new high-performance materials that don’t contain toxic elements.
(note 4)Seebeck effect
Phenomenon in which a voltage is generated when a temperature difference is applied to a solid. The EMF per 1°C of milan米兰体育官网入口 the Seebeck coefficient.
About milan米兰体育官网入口 Group
milan米兰体育官网入口 (TSE; 5801, ISIN; JP3827200001) Group started business in 1884, when its copper-smelting facility and wire manufacturing factory was established. Since then milan米兰体育官网入口 has become pioneers in the latest technologies by addressing diverse technological issues. milan米兰体育官网入口 has released products in a number of areas, including telecommunications, electronics, automobiles, and construction, with the three types of materials it works with at their core, namely, optics, plastics, and metals. Many of these products have attained the top global market share, and all of its products have contributed to society in numerous business areas. milan米兰体育官网入口 reported consolidated revenues of JPY 843.3 billion (approximately USD 7.8B) for the fiscal year ended March 31, 2017.